Disruption of the Homobimetallic Anion. PPN⁺(ŋ⁵ - MeCp)Mn(CO)₂Mn(CO)₅⁻ by Ethyl Bromide
Disruption of the Homobimetallic Anion. PPN⁺(ŋ⁵ - MeCp)Mn(CO)₂Mn(CO)₅⁻ by Ethyl Bromide
- 강원대학교 기초과학연구소
- 기초과학연구
- 제15집
-
2004.12230 - 244 (15 pages)
- 0
It is widely accepted that most homobimetallic complexes show covalent character in their metal-metal bonds; however, PPN？(ŋ？ - MeCp)Mn(CO)₂Y1n(CO)？？" is likely to have a donor-acceptor metal-metal bond character as most heterobimetallic complexes have shown. This compound was disrupted by alkyl halide in THF under a nitrogen atmosphere at various temperatures by using the pseudo first order reaction condition where on excess of ethyl bromide was employed. This reaction is overall second order with respect to [homobimetallic complex] and [ethyl bromide].
Abstract<BR>1. Introduction<BR>2. Experimental<BR>3. Results and Discussion<BR>4. Conclusions<BR>5. Acknowledgement<BR>6. References<BR>
(0)
(0)