Luminescence characterization of (Ca₁−xSrx)(S₁−ySey):Eu²⁺,M³⁺ (M= Sc and Y) for high color rendering white LED

The highly efficient red phosphors (Ca1−xSrx)(S1−ySey):Eu²⁺,M³⁺ (M= Sc and Y) were prepared, starting from CaCO₃, SrCO₃, Eu₂O₃, Sc₂O₃, Y₂O₃, S, and SeO₂ with a flux, by a conventional solid-state reaction. The optimized red phosphors converted 11.8% (Sc³⁺) and 11.7% (Y³⁺) of the absorbed blue light into luminescence. These quantum values are much higher than Q= 3.0% of CaS:Eu²⁺. For the fabrication of light-emitting diodes (LEDs), the prepared phosphors were coated with MgO from non-aqueous solution to overcome their weakness against moisture. White LEDs were fabricated by pasting the prepared red phosphors and the yellow YAG:Ce³⁺ phosphor on an InGaN blue chip (λems = 446.5 nm). The incorporation of the red phosphor to the YAG:Ce³⁺ phosphor resulted in an improved color rendering index (Ra) from 70 to 80.