학술저널
3-Haloindolenine의 반응성에 관한 연구(I)
Reactivity of 3-Haloindolenines (I)
- 대한약학회
- 약학회지
- 제25권 제3호 (1981년)
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1981.0983 - 87 (5 pages)
- 3
Reaction of 3-chloroindolenine with acetic acid gives oxindole and acetoxyindole. Similar treatment of 3-bromoindolenine affords 6-bromoindole. Reaction of 3-chloro-and 3-bromoindolenine with methanolic sodium hydroxide gives 3-methoxyindolenine, 2-methoxyindolenine and oxindole. Thermal reaction of 3-bromoindolenine in 1, 1'', 2, 2''-tetrachloroethane gives 6-bromoindole but no reaction is occurred in 3-chloro-indolenine. Photolysis of 3-chloroindolenine gives indole, 4-, 5- and 7-chloroindole.
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