Differential Pulse Anodic Stripping Voltammetry법에 의한 게르마늄 분석에 관한 연구(제1보)

Determination of Germanium(IV) by Differential Pulse Anodic Stripping Voltammetry(I)

Voltammetric deposition and differential pulse anodic stripping (DPASV) of Ge(IV)at a gold electrode was investigated. Germanium(IV) exhibits two stripping peaks by DPASV in sodium borate solution, the first peak at about -1.1v. vs SCE and the second one, in the range of -0.6 to -0.2v. vs SCE. Factors affecting the sensitivity and precision included the nature of working electrode, supporting electrolytes, deposition potential, deposition time, pH, pulse height, voltage scan rate. The relative standard deviation of the measurements of the peak currents, for 100ng/ml Ge(IV), was less than +/-3%. The detection limit of Ge (IV) was 0.01ng/ml. Percent recovery in the extraction procedure of Ge (IV) from matrices by benzene in c-HCl, followed by back extraction with saturated borax solution, ranged from 96 to 104%.