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1-Isonicotnyl-2-furfurylidene Hydrazine-Cd(II) 착화합물에 관한 분석화학적연구

Spectrophotometric Study of the Cadmium (II) Complex of 1-Isonicotinyl-2-furfurylidene Hydrazine

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A new organic reagent, 1-isonicotynyl-2-furfurylidene hydrazine synthesized from isonicotinic acid hydrazid and furfural, gives yellow liquid with cadmium (II). Cadmium complex of the reagent is soluble in water with yellow coloratiop. The complex has a maximum absorption at 363mmc and molar ratio of cadmium to reagent was estimated as 1 : 1 by continuous variation method and slope method. Molecular extinction coefficient and apparent formation constant of this complex was spectrophotometrically determined. K=4.48 X 103 (Babko''s method) K=1.33 X 103 (Anderson''s method)

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