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alpha-치환 톨루엔 유도체의 13C NMR 화학 Shift

13C NMR Chemical Shifts of alpha-Substituted Toluenes)

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13C NMR chemical shifts for 18 alpha-susbstituted toluenes at high dilution in CCl4 solution have been determined. Substituents are as follows: H, Me, Et, n-Pr, iso-Pr, Ph, F, Cl, Br, NH2, NHMe, NMe2, OH, OMe, OCOMe, C02Me, C02Et, CN. Those chemical shifts of the methylene carbon of the toluene and the alpha-carbon of the n-butane systems are correlated well. (r=.975, slope=.962)

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