학술저널
4-데옥시로도마이시논 유도체의 합성
Synthesis of 4-Deoxyrhodomycinone Derivatives
- 대한약학회
- 약학회지
- 제41권 제1호 (1997년)
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1997.017 - 13 (7 pages)
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A regiospecific total synthesis on the precursor(18b) of rhodomycinones is described. The anion of 3-carbomethoxy-1(3H)-isobenzofuranone(13) was respectively condensed with naphthalenone (12) and butenoate(8) derivatives which were, prepared by two different synthetic routes to afford 9-ethyl-6,7-dihydroxy 7,8,9,10-tetrahydronaphthacene-5,12 dione(18b) after oxidation and reduction.
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