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염화철 처리 활성탄에 의한 질산염 제거

Nitrate Removal by FeCl3-Treated Activated Carbon

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A laboratory experiment was performed to invstigate the nitrate removal using FeCl3 -treated activated carbon. Iron chloride(III) was coated onto the surface of activated carbon. The removal efficiency of nitrate was increased with increasing of FeCl3 was used for coating material. About 22~26mg of Fe per unit g of activated carbon was adsorbed. The nitrate removal was not affected by the pH under the experiment range of pH, but the pH value in solution decrease to 3.5~4.0 after reaction. The removal efficiency of nitrate was increased with increasing of dosage of adsorbents. Ammonia was not detected and the Fe concentration as low as 0.22mg/ℓ was desorbed from the adsorbents. The adsorbents was regenerated using KCl solution, and recovery was 76.6% at 1 M of KCl. The adsorption of nitrate by FeCl3-treated activated carbon followed the Freundlich isotherm equation and the Freundlich constant, 1/n, was 0.346. These results showed that the FeCl3-treated activated carbon could serve as the basis of a useful nitrate removal.

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