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FAB/MS를 이용한 Benzoxazolo Carbocyanine계 화합물의 분석

Analysis of Benzoxazolo Carbocyanine Compounds using FAB/Mass Spectrometry

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Benzoxazolo carbocyanine compounds were synthesized by condensation of a suitable ortho-ester with an appropriately substituted 2-methylbenzoxazole in the presence of triethylamine. This compounds used as green sensitizing dyes in photographic emulsions. The compounds are characterized by fast atom bombardment mass spectrometry. The values(m/z) of structurally significant ions observed in FAB spectra. It was showed tentative fragmentation pattern in FAB spectroscopy of HN(C2H5)3 cations in glycerol/trifluoroacetic acid matrix.

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