디엘레트地域 스카른의 岩石學的 成因硏究

Petrogenesis of the skarn at the Dielette, Cotentin, France

Skarn at the Dielette formed largely in calc-silicate hornfels at the contact with the Flamanville granite. The skarn consists mainly of garnet and pyroxene, and less frequently vesuvianite. Traversing toward calc-silicate hornfels wall rock from a central zone of the skarn, the general sequence of formation of mineral assemblages is: (1) dark brown garnet (2) pale brown garnet-vesuvianite-pyroxene, and (3) pyroxene-prehnite-scapolite-wollastonite envelopes (designated as transition zone) developed between skarn and calc-silicate hornfels. The central zone of the skarn consists mainly of dark brown garnets (garnet Ⅰ) that contain little or no pyroxene. The pale brown garnet (garnet Ⅱ) is associated with pyroxene and vesuvianite. The sequence of these garnets results from the zonal growth outward. There is an abrupt discontinuity in composition between garnet Ⅰ formed in early stage and garnet Ⅱ in late stage, while each garnet shows relatively uniform composition. At the zone in contact with the granite, the iron contents of garnets decrease toward the marginal zone of the skarn, from an average value of 36 mole % andradite in garnet Ⅰ to 18 mole % andradite in garnet Ⅱ. At the zone distant from the granite, the andradite component decreases from 28 mole % in garnet Ⅰ to 19 mole % in garnet Ⅱ. The variation of the iron contents of pyroxenes is also similar to that of garnets. The sharp discontinuity in composition of garnets and pyroxenes suggests that the skarn of study area was formed by infiltration metasomatic process. The results of the analyses of mineral assemblages of the transition zone by chemical potential diagrams suggest that the transition zone was made by the diffusion of the elements Ca, K and Fe from the skarn to the calc-silicate hornfels contact zone. The estimated temperatures and Xco₂ for the formation of the transition zone show 300℃＜Temp.＜440℃ and 0.07±0.05＜Xco₂＜0.02±0.01 at 1 Kb respectively.