Calculation of the Magnetic Moments and the Dipolar Shifts for d$^1$ and d$^2$Complexes in a Strong Ligand Field of Trigonal Symmetry

Calculation of the Magnetic Moments and the Dipolar Shifts for d$^1$ and d$^2$Complexes in a Strong Ligand Field of Trigonal Symmetry

A method to calculate the magnetic moments for $d^1$ and $d^2$ complexes in a strong crystal field of trigonal symmetry has been developed in this work choosing the trigonal axis (Ⅲ) as the quantization axis. The calculated magnetic moments using this method for $d^1$ and $d^2$ complexes in a strong trigonal ligand field fall in the range of the experimental values. The dipolar shifts for $d^1$ and $d^2$ complexes in a strong trigonal ligand field are also calculated using the calculated magnetic susceptibility components. The calculated values of the dipolar shifts also fall in the reasonable range.