Ab initio Study on Structures, Energies and Vibrations of Methylammonium-(water)$_n$ (n=1-3) Complexes
Ab initio Study on Structures, Energies and Vibrations of Methylammonium-(water)$_n$ (n=1-3) Complexes

대한화학회
Bulletin of the Korean Chemical Society
Vol.22 No.6
2001.01

597 - 604 (8 pages)

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외부링크

The reaction of [(2-N,N-dimethylaminomethyl) pheny] methylvinychlorosiane with t-BuLi in hexane solvent gave dimers, five isomeric 1,3-disilacyslobutanes which were weparated and charaterized. In trapping experiments with various trapping agents, no corresponding silene-trapping aduct was observed. We suggest that more important species for the formation of five isomeric dimers might be the zwitterionic species generated by virtue of intramolecular donor atom rather than the silene.

Ab initio Study on Structures, Energies and Vibrations of Methylammonium-(water)$_n$ (n=1-3) Complexes
Ab initio Study on Structures, Energies and Vibrations of Methylammonium-(water)$_n$ (n=1-3) Complexes

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Ab initio Study on Structures, Energies and Vibrations of Methylammonium-(water)$_n$ (n=1-3) Complexes Ab initio Study on Structures, Energies and Vibrations of Methylammonium-(water)$_n$ (n=1-3) Complexes

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Ab initio Study on Structures, Energies and Vibrations of Methylammonium-(water)$_n$ (n=1-3) Complexes
Ab initio Study on Structures, Energies and Vibrations of Methylammonium-(water)$_n$ (n=1-3) Complexes